HCID 23668465, compound → HCID 131719323, compound

HRID 1440904Notes

Reaction equation

HRID 1440904 reaction equation
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].[Br-].[CH2:26]([C:30]([CH2:34][CH2:35][CH2:36][CH3:37])=[CH:31][CH2:32][SH2+:33])[CH2:27][CH2:28][CH3:29]>O>[CH2:26]([C:30]([CH2:34][CH2:35][CH2:36][CH3:37])=[CH:31][CH2:32][SH2+:33])[CH2:27][CH2:28][CH3:29].[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 23668465HCID 23668465, compoundHCID 88360701HCID 88360701, compound

Product 1

HCID 131719323HCID 131719323, compoundYield 87.8%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

An aqueous solution of 5.00 g of lithium butyltriphenylborate in 100 ml of water was added to an aqueous solution of 4.36 g of dibutylallylsulfonium bromide in 200 ml of water, and the resultant mixture was stirred at room temperature for 30 minutes. Then, the reaction mixture was filtered, and the resultant crystal was washed with water and dried to give 6.97 g of dibutylallylsulfonium-butyltriphenylborate.

Workup

  1. filtrationThen, the reaction mixture was filtered
  2. washthe resultant crystal was washed with water
  3. customdried

Sources & evidence

ORD record
ord-5eab7afc8742493fb951a33db8f2862d
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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