HCID 23668465, compound → HCID 19047907, compound

HRID 1440905Notes

Reaction equation

HRID 1440905 reaction equation
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].[I-].[CH3:26][S+:27]([CH3:31])[CH2:28][C:29]#[N:30]>O>[CH3:26][S+:27]([CH3:31])[CH2:28][C:29]#[N:30].[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 23668465HCID 23668465, compoundHCID 88360358HCID 88360358, compound

Product 1

HCID 19047907HCID 19047907, compoundYield 68.4%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

An aqueous solution of 5.00 g of lithium butyltriphenylborate in 100 ml of water was added to an aqueous solution of 3.74 g of dimethylcyanomethylsulfonium iodide in 200 ml of water, and the resultant mixture was stirred at room temperature for 30 minutes. Then, the reaction mixture was filtered, and the resultant crystal was washed with water and dried to give 4.48 g of dimethylcyanomethylsulfonium-butyltriphenylborate.

Workup

  1. filtrationThen, the reaction mixture was filtered
  2. washthe resultant crystal was washed with water
  3. customdried

Sources & evidence

ORD record
ord-f0de42843b234b5795df3ed6bb197f85
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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