HCID 23668465, compound → HCID 18982488, compound

HRID 1440908Notes

Reaction equation

HRID 1440908 reaction equation
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].[I-].[CH3:26][S+:27]([CH3:31])[CH2:28][S:29][CH3:30]>O>[CH3:26][S+:27]([CH3:31])[CH2:28][S:29][CH3:30].[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

4

Reactant 2

HCID 23668465HCID 23668465, compoundHCID 131719325HCID 131719325, compound

Product 1

HCID 18982488HCID 18982488, compoundYield 72%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

An aqueous solution of 5.00 g of lithium butyltriphenylborate in 100 ml of water was added to an aqueous solution of 4.08 g of dimethymethyl thiomethylsulfonium iodide in 200 ml of water, and the resultant mixture was stirred at room temperature for 30 minutes. Then, the reaction mixture was filtered, and the resultant crystal was washed with water and dried to give 4.96 g of dimethylmethylthiomethylsulfonium-butyltriphenylborate.

Workup

  1. filtrationThen, the reaction mixture was filtered
  2. washthe resultant crystal was washed with water
  3. customdried

Sources & evidence

ORD record
ord-af485d2e32834fdc8173a2b2189868e8
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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