Water → HCID 18982513, compound

HRID 1440911Notes

Reaction equation

HRID 1440911 reaction equation
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].[CH3:25][S+:26]([CH3:35])([O:28][C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1)=[O:27].O>C(#N)C.CC(C)=O>[CH3:25][S+:26]([CH3:35])([O:28][C:29]1[CH:30]=[CH:31][CH:32]=[CH:33][CH:34]=1)=[O:27].[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

6

Reactant 3

HCID 962WaterHCID 18982514HCID 18982514, compoundHCID 23668465HCID 23668465, compound

Product 1

HCID 18982513HCID 18982513, compoundYield 32.5%

Reagents, catalysts & solvents 2

HCID 180AcetoneSolventHCID 6342AcetonitrileSolvent

Procedure

A solution of 3.00 g of lithium butyltriphenylborate in 100 ml of acetonitrile was added to a solution of 3.10 g of dimethylphenoxyoxosulfonium bexafluorophosphate in 100 ml of acetone, and the resultant mixture was stirred at room temperature for 30 minutes. The reaction mixture was poured into 500 ml of water, and the resultant oily component was separated, recovered, washed with water and recrystallized from dichloromethane/ether to give 1.50 g of dimethylphenoxyoxosulfonium-butyltriphenylborate.

Workup

  1. customthe resultant oily component was separated
  2. customrecovered
  3. washwashed with water
  4. customrecrystallized from dichloromethane/ether

Sources & evidence

ORD record
ord-47abd23cb9964775934e30447fc743ca
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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