Water → HCID 18982381, compound

HRID 1440912Notes

Reaction equation

HRID 1440912 reaction equation
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].Cl([O-])(=O)(=O)=O.[CH3:30][S+:31]([CH3:39])[C:32]1[CH:37]=[CH:36][C:35]([CH3:38])=[CH:34][CH:33]=1.O>C(#N)C>[CH3:30][S+:31]([CH3:39])[C:32]1[CH:37]=[CH:36][C:35]([CH3:38])=[CH:34][CH:33]=1.[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

5

Reactant 3

HCID 962WaterHCID 18982384Dimethyl(4-methylphenyl)sulfanium perchlorateHCID 23668465HCID 23668465, compound

Product 1

HCID 18982381HCID 18982381, compoundYield 38.3%

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent2×

Procedure

A solution of 3.00 g of lithium butyltriphenylborate in 100 ml of acetonitrile was added to a solution of 2.79 g of dimethyl-p-tolylsulfonium perchlorate in 100 ml of acetonitrile, and the resultant mixture was stirred at room temperature for minutes. The reaction mixture was poured into 500 ml of water, and the resultant oily component was separated, recovered, washed with water and recrystallized from dichloromethane/ether to give 1.70 g of dimethyl-p-tolylsulfonium-butyltriphenylborate.

Workup

  1. customthe resultant oily component was separated
  2. customrecovered
  3. washwashed with water
  4. customrecrystallized from dichloromethane/ether

Sources & evidence

ORD record
ord-9fbccd3092b7467b91c2c4c233c45dce
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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