Water → HCID 18982355, compound

HRID 1440914Notes

Reaction equation

HRID 1440914 reaction equation
[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)[CH2:2][CH2:3][CH3:4].[Li+].[Cl-].[CH3:26][S+:27]([CH3:35])[NH:28][C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1.O>C(#N)C.CO>[CH3:26][S+:27]([CH3:35])[NH:28][C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1.[CH2:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[CH2:2][CH2:3][CH3:4]

Participants

6

Reactant 3

HCID 962WaterHCID 23668465HCID 23668465, compoundHCID 88398099HCID 88398099, compound

Product 1

HCID 18982355HCID 18982355, compoundYield 45.2%

Reagents, catalysts & solvents 2

HCID 887MethanolSolventHCID 6342AcetonitrileSolvent

Procedure

A solution of 3.00 g of lithium butyltriphenylborate in 100 ml of acetonitrile was added to a solution of 1.86 g of dimethyl-N-phenylaminosulfonium chloride in 100 ml of methanol, and the resultant mixture was stirred at room temperature for 30 minutes. The reaction mixture was poured into 500 ml of water, and the resultant oily component was separated, recovered, washed with water and recrystallized from dichloromethane/ether to give 2.01 g of dimethyl-N-phenylaminosulfonium-butyltriphenylborate.

Workup

  1. customthe resultant oily component was separated
  2. customrecovered
  3. washwashed with water
  4. customrecrystallized from dichloromethane/ether

Sources & evidence

ORD record
ord-8558526b8b1c43d3862550ff0f1cfd47
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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