Water → HCID 18982582, compound

HRID 1440916Notes

Reaction equation

HRID 1440916 reaction equation
[CH:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)([CH2:3][CH3:4])[CH3:2].[Li+].F[P-](F)(F)(F)(F)F.[C:32]([C:36]1[CH:41]=[CH:40][C:39]([S+:42]([C:52]2[CH:57]=[CH:56][C:55]([C:58]([CH3:61])([CH3:60])[CH3:59])=[CH:54][CH:53]=2)[CH2:43][C:44]([C:46]2[CH:51]=[CH:50][CH:49]=[CH:48][CH:47]=2)=[O:45])=[CH:38][CH:37]=1)([CH3:35])([CH3:34])[CH3:33].O>C(#N)C>[C:32]([C:36]1[CH:41]=[CH:40][C:39]([S+:42]([C:52]2[CH:57]=[CH:56][C:55]([C:58]([CH3:61])([CH3:60])[CH3:59])=[CH:54][CH:53]=2)[CH2:43][C:44]([C:46]2[CH:51]=[CH:50][CH:49]=[CH:48][CH:47]=2)=[O:45])=[CH:38][CH:37]=1)([CH3:35])([CH3:34])[CH3:33].[CH:1]([B-:5]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([C:6]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:11]=1)[C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1)([CH2:3][CH3:4])[CH3:2]

Participants

5

Reactant 3

HCID 962WaterHCID 18982507HCID 18982507, compoundHCID 131719327HCID 131719327, compound

Product 1

HCID 18982582HCID 18982582, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent2×

Procedure

A solution of 2.61 g of lithium sec-butyltriphenylborate in 50 ml of acetonitrile was added to solution of 5.00 g of bis(p-tert-butylphenyl)phenacylsulfonium hexafluorophosphate in 100 ml of acetonitrile and the resultant mixture was stirred at room temperature for 30 minutes. Then, 200 ml of water was added. The resultant precipitate of a yellow oily component was recovered, and 100 ml of dichloromethane was added. The dichloromethane layer was washed with water, dried and concentrated to give 4.32 of bis(p-tert-butylphenyl)phenacylsulfonium-(sec-butyl)triphenylborate.

Workup

  1. customThe resultant precipitate of a yellow oily component was recovered
  2. addition100 ml of dichloromethane was added
  3. washThe dichloromethane layer was washed with water
  4. customdried
  5. concentrationconcentrated

Sources & evidence

ORD record
ord-5e2191fd94624bbdb2d1003f03ef3768
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

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