Water → HCID 18982396, compound

HRID 1440921Notes

Reaction equation

HRID 1440921 reaction equation
[C:1]([B-:5]([CH2:10][CH3:11])([CH2:8][CH3:9])[CH2:6][CH3:7])([CH3:4])([CH3:3])[CH3:2].[Li+].F[As-](F)(F)(F)(F)F.[C:20]1([S+:26]([C:37]2[C:38]3[C:43]([CH:44]=[C:45]4[C:50]=2[CH:49]=[CH:48][CH:47]=[CH:46]4)=[CH:42][CH:41]=[CH:40][CH:39]=3)[CH2:27][C:28]([C:30]2[CH:35]=[CH:34][C:33]([Cl:36])=[CH:32][CH:31]=2)=[O:29])[CH:25]=[CH:24][CH:23]=[CH:22][CH:21]=1.O>C(#N)C>[C:20]1([S+:26]([C:37]2[C:50]3[C:45]([CH:44]=[C:43]4[C:38]=2[CH:39]=[CH:40][CH:41]=[CH:42]4)=[CH:46][CH:47]=[CH:48][CH:49]=3)[CH2:27][C:28]([C:30]2[CH:31]=[CH:32][C:33]([Cl:36])=[CH:34][CH:35]=2)=[O:29])[CH:21]=[CH:22][CH:23]=[CH:24][CH:25]=1.[C:1]([B-:5]([CH2:10][CH3:11])([CH2:6][CH3:7])[CH2:8][CH3:9])([CH3:2])([CH3:4])[CH3:3]

Participants

5

Reactant 3

HCID 962WaterHCID 18982574HCID 18982574, compoundHCID 131719318HCID 131719318, compound

Product 1

HCID 18982396HCID 18982396, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent2×

Procedure

A solution of 1.29 g of lithium tert-butyltriethylborate in 50 ml of acetonitrile was added to a solution of 5.00 g of phenyl(9-anthryl)(p-chlorophenacyl)sulfonium hexafluoroarsenate in 100 ml of acetonitrile, and the resultant mixture was stirred at room temperature for 30 minutes. Then, 200 ml of water was added. The resultant precipitate of a yellow oily component was recovered, and 100 ml of dichloromethane was added. The dichloromethane layer was washed with water, dried and concentrated to give 2.43 of phenyl(9-anthryl)(p-chlorophenacyl)sulfonium-(tert-butyl)triethylborate.

Workup

  1. customThe resultant precipitate of a yellow oily component was recovered
  2. addition100 ml of dichloromethane was added
  3. washThe dichloromethane layer was washed with water
  4. customdried
  5. concentrationconcentrated

Sources & evidence

ORD record
ord-26fd1d9315c646e883e45eab498dd9be
Source dataset
uspto-grants-1996_03
Patent number
US05500453

Reaction notes

Loading…