Water → HCID 15332559, compound

HRID 1441001Notes

Reaction equation

HRID 1441001 reaction equation
[OH2:1].S(=O)(=O)(O)O.[Cl:7][C:8]1[CH:13]=[C:12]([Cl:14])[CH:11]=[CH:10][C:9]=1[CH2:15][CH2:16][CH2:17][CH2:18][OH:19]>CC(C)=O.[O-2].[O-2].[O-2].[Cr+6]>[Cl:7][C:8]1[CH:13]=[C:12]([Cl:14])[CH:11]=[CH:10][C:9]=1[CH2:15][CH2:16][CH2:17][C:18]([OH:1])=[O:19]

Participants

6

Reactant 3

HCID 962Water2×HCID 1118Sulfuric AcidHCID 15332558HCID 15332558, compound

Product 1

HCID 15332559HCID 15332559, compound

Reagents, catalysts & solvents 2

HCID 10219390chromium (VI) trioxideCatalystHCID 180AcetoneSolvent

Procedure

By the method of Example 1, Step A, 3.63 g (0.0363 mole) of chromium trioxide, 5 mL of water, 5.6 g (0.056 mole) of 18M sulfuric acid, 10.4 mL of water, and 11.4 g (0.052 mole) of 4-(2,4-dichlorophenyl)-1-butanol in 332 mL of acetone are reacted, yielding 4-(2,4-dichlorophenyl)butanoic acid.

Sources & evidence

ORD record
ord-06fd9f0b407045a18ea1da91158898c9
Source dataset
uspto-grants-1996_03
Patent number
US05502054

Reaction notes

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