HuagongsheHuagongshe Chemistry Print Report · For research reference only
alpha-D-Glucopyranosyl bromide, tetraacetate → HCID 67351076, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | alpha-D-Glucopyranosyl bromide, tetraacetate | HCID 101776 | — |
| Reactant | ((2R,3R,4S,5R,6R)-6-bromo-3,4,5-tris(2,2-dimethylpropanoyloxy)oxan-2-yl)methyl 2,2-dimethylpropanoate | HCID 10886360 | — |
| Reactant | 4-[(4-benzyloxy-2-methylphenyl)methyl]-1,2-dihydro-5-isopropyl-3H-pyrazol-3-one | HCID 67351077 | — |
| Reactant | HCID 68535856 | HCID 68535856 | — |
| Product | HCID 67351076 | HCID 67351076 | — |
Reaction Steps
The title compound was prepared in a similar manner to that described in Reference Example 12 using 4-[(4-benzyloxy-2-methylphenyl)methyl]-1,2-dihydro-5-isopropyl-3H-pyrazol-3-one and 2,3,4,6-tetra-O-pivaloyl-α-D-glucopyranosyl bromide (Kunz, H.; Harreus, A. Liebigs Ann. Chem. 1982, 41-48 Velarde, S.; Urbina, J.; Pena, M. R. J. Org. Chem. 1996, 61, 9541-9545) instead of 4-{[4-(2-benzyloxycarbonyl-2-methylpropoxy)phenyl]-methyl}-1,2-dihydro-5-isopropyl-3H-pyrazol-3-one and acetobromo-α-D-glucose, respectively.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07655632B2 |
| Source dataset | uspto-grants-2010_02 |
| ORD ID | ord-ef3fc7d994174f9abf2ab24fdc672067 |
| Source note | uspto-grants-2010_02 |