HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 58610096, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 1,4-Dicyanobenzene | HCID 12172 | — |
| Reactant | Benzoic acid, 2-mercapto-, methyl ester | HCID 21009 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 58610096 | HCID 58610096 | 32% |
Reaction Steps
A mixture of terephthalonitrile (1.50 g, 12 mmol), methyl thiosalicylate (2.95 g, 18 mmol), triethylamine (2.10 g, 21 mmol) and toluene (20 ml) was heated and refluxed under a nitrogen flow for 48 hours. The crystals precipitated were taken by filtration and recrystallized from tetrahydrofuran to give the title compound (0.98 g, 32%) as crystals.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07659267B2 |
| Source dataset | uspto-grants-2010_02 |
| ORD ID | ord-4f6072976cd54a14b864edb8e38cf122 |
| Source note | uspto-grants-2010_02 |