Potassium Nitrate → HCID 59168392, compound

HRID 1443922Notes

Reaction equation

HRID 1443922 reaction equation
[CH:1]1[CH:13]=[CH:12][C:11]2[CH2:14][CH2:15][CH2:16][N:9]3[C:10]=2[C:2]=1[C:3]1[CH2:4][CH2:5][CH2:6][CH2:7][C:8]=13.[N+:17]([O-])([O-:19])=[O:18].[K+]>S(=O)(=O)(O)O>[N+:17]([C:13]1[CH:1]=[C:2]2[C:10]3=[C:11]([CH2:14][CH2:15][CH2:16][N:9]3[C:8]3[CH2:7][CH2:6][CH2:5][CH2:4][C:3]2=3)[CH:12]=1)([O-:19])=[O:18]

Participants

4

Reactant 2

HCID 24434Potassium NitrateHCID 12368960HCID 12368960, compound

Product 1

HCID 59168392HCID 59168392, compound

Reagents, catalysts & solvents 1

HCID 1118Sulfuric AcidSolvent

Procedure

Following the procedure of Example 1, step 2, 5,6,8,9,10,11-hexahydro-4H-pyrido[3,2,1-jk]carbazole (1.7 g, 8.0 mmol) and potassium nitrate (0.80 g, 8.0 mmol) in concentrated sulfuric acid (20 mL) provided 2-nitro-5,6,8,9,10,11-hexahydro-4H-pyrido[3,2,1-jk]carbazole. MS (ES) m/z 257.1.

Sources & evidence

ORD record
ord-24fff305c93a45e4a25c06ac4a6b5628
Source dataset
uspto-grants-2010_02
Patent number
US07662831B2

Reaction notes

Loading…