HCID 59168392, compound → HCID 59168390, compound

HRID 1443923Notes

Reaction equation

HRID 1443923 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]2[C:14]3=[C:15]([CH2:17][CH2:18][CH2:19][N:13]3[C:12]3[CH2:11][CH2:10][CH2:9][CH2:8][C:7]2=3)[CH:16]=1)([O-])=O>[Pd].C(O)C>[CH:5]1[C:4]([NH2:1])=[CH:16][C:15]2[CH2:17][CH2:18][CH2:19][N:13]3[C:14]=2[C:6]=1[C:7]1[CH2:8][CH2:9][CH2:10][CH2:11][C:12]=13

Participants

4

Reactant 1

HCID 59168392HCID 59168392, compound

Product 1

HCID 59168390HCID 59168390, compound

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

Following the procedure of Example 1, Step 3, 2-nitro-5,6,8,9,10,11-hexahydro-4H-pyrido[3,2,1-jk]carbazole (1.1 g, 4.3 mmol) and 5% palladium on carbon (0.10 g) in ethanol (70 mL) was hydrogenated to provide 5,6,8,9,10,11-hexahydro-4H-pyrido[3,2,1-jk]carbazol-2-amine.

Sources & evidence

ORD record
ord-ca381d01b84145319e0d1b62bb1112bb
Source dataset
uspto-grants-2010_02
Patent number
US07662831B2

Reaction notes

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