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HRID1444288

反应详情

EQUATION

反应方程式

HRID 1444288 的结构方程式

REACTANTS

反应物

2
结构：[CH3][Sn]([CH3])([CH3])[N]=[N+]=[N-]
HCID5104973

Azidotrimethyltin(IV)

C3H9N3Sn

结构：N#CCc1cccc(NC(=O)c2ccc(Br)o2)c1
HCID59654859

未命名化合物

PRODUCTS

生成物

1
结构：O=C(Nc1cccc(Cc2nnn[nH]2)c1)c1ccc(Br)o1
HCID178522031

未命名化合物

PROCEDURE

实验过程

Nitrile (83) (162 mg, 0.53 mmol) was treated with Me3SnN3 using Method K. The residue was purified by column chromatography, flushing with heptane (200 ml) and eluting with 50% EtOAc in heptane to give the title compound.

WORKUP

后处理

  1. customThe residue was purified by column chromatography
  2. customflushing with heptane (200 ml)
  3. washeluting with 50% EtOAc in heptane