Zincchloride → HCID 12941755, compound

HRID 1447083Notes

Reaction equation

HRID 1447083 reaction equation
[OH:1][CH:2]([CH2:14][O:15][CH:16]([CH3:18])[CH3:17])[CH2:3][N:4]([CH2:8][CH2:9][NH:10][C:11](=[S:13])[S-:12])[C:5](=[S:7])[S-:6].[Na+].[Na+].[Cl-].[Zn+2:22].[Cl-]>O>[OH:1][CH:2]([CH2:14][O:15][CH:16]([CH3:18])[CH3:17])[CH2:3][N:4]([CH2:8][CH2:9][NH:10][C:11](=[S:12])[S-:13])[C:5](=[S:6])[S-:7].[Zn+2:22]

Participants

4

Reactant 2

HCID 3007855ZincchlorideHCID 12941750HCID 12941750, compound

Product 1

HCID 12941755HCID 12941755, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

In 200 ml of water, 47 g (0.05 mol) of an aqueous 40% sodium N-(2-hydroxy-3-isopropoxypropyl)-ethylenebisdithiocarbamate was stirred at room temperature. To the resultant aqueous solution, 13.6 g (0.05 mol) of an aqueous 50% zinc chloride solution was gradually added dropwise. After the dropwise addition, the reaction solution was stirred continuously for three hours at room temperature. The crystals which consequently educed in the solution were separated by filtration and washed with water. The washed crystals were dried at 50° to 60° C. under a vacuum. Thus was obtained zinc N-(2-hydroxy-3-isopropoxypropyl)-ethylenebisdithiocarbamate (Compound No. 6). Copper, iron, nickel, cobalt, tin, calcium or magnesium salt could easily be produced by using the water-soluble salt of copper, iron, nickel, cobalt, tin, calcium, or magnesium in the equivalent weight in place of zinc chloride. The compounds prepared by the procedure described above were as shown below.

Workup

  1. additionAfter the dropwise addition
  2. customwere separated by filtration
  3. washwashed with water
  4. customThe washed crystals were dried at 50° to 60° C. under a vacuum

Sources & evidence

ORD record
ord-1d8f25fd5d1e443ea805dfc125981dca
Source dataset
uspto-grants-1982_02
Patent number
US04315846

Reaction notes

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