Ammonia → HCID 22819292, compound

HRID 1447433Notes

Reaction equation

HRID 1447433 reaction equation
[C:1]1([C@@H:7]2[CH2:11][NH:10][C@H:9]([C:12]([OH:14])=[O:13])[CH2:8]2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[Li].N>>[C:1]1([C@@H:7]2[CH2:11][NH:10][C@H:9]([C:12]([OH:14])=[O:13])[CH2:8]2)[CH2:2][CH:3]=[CH:4][CH2:5][CH:6]=1

Participants

4

Reactant 3

HCID 222AmmoniaHCID 3028194LithiumHCID 11160513HCID 11160513, compound

Product 1

HCID 22819292HCID 22819292, compound

Procedure

cis-4-Phenyl-L-proline is treated with lithium and ammonia according to the procedure of Example 1 of U.S. Pat. No. 3,485,819 to yield cis-4-(1,4-cyclohexadienyl)-L-proline.

Sources & evidence

ORD record
ord-c38cdeceb2b54fb9aa91d7a4c9ff319c
Source dataset
uspto-grants-1982_02
Patent number
US04316905

Reaction notes

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