HCID 22819292, compound → HCID 53785135, compound
Reaction equation
[C:1]1([C@@H:7]2[CH2:11][NH:10][C@H:9]([C:12]([OH:14])=[O:13])[CH2:8]2)[CH2:6][CH:5]=[CH:4][CH2:3][CH:2]=1.[H][H]>[C].[Pd]>[C:1]1([C@@H:7]2[CH2:11][NH:10][C@H:9]([C:12]([OH:14])=[O:13])[CH2:8]2)[CH2:6][CH2:5][CH2:4][CH2:3][CH:2]=1Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
cis-4-(1,4-Cyclohexadienyl)-L-proline is treated with a palladium-carbon catalyst and shaken on a Parr hydrogenator under 3 atmospheres of hydrogen to yield cis-4-(1-cyclohexenyl)-L-proline.
Sources & evidence
- ORD record
- ord-03d18231127d4b95b18b882a88d73bdb
- Source dataset
- uspto-grants-1982_02
- Patent number
- US04316905
Reaction notes
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