Ammonia → HCID 22819377, compound

HRID 1447448Notes

Reaction equation

HRID 1447448 reaction equation
C([S:4][CH2:5][CH2:6][CH2:7][C:8]([N:10]1[CH2:17][C@@H:16]([O:18][CH3:19])[CH2:15][C@H:11]1[C:12]([OH:14])=[O:13])=[O:9])(=O)C.N>>[SH:4][CH2:5][CH2:6][CH2:7][C:8]([N:10]1[CH2:17][C@@H:16]([O:18][CH3:19])[CH2:15][C@H:11]1[C:12]([OH:14])=[O:13])=[O:9]

Participants

3

Reactant 2

HCID 222AmmoniaHCID 54469246HCID 54469246, compound

Product 1

HCID 22819377HCID 22819377, compound

Procedure

Hydrolysis of (cis)-1-(4-acetylthio-1-oxobutyl)-4-methoxy-L-proline with an aqueous ammonia solution according to the procedure of Example 2 yields 1-(4-mercapto-1-oxobutyl)-cis-4-methoxy-L-proline.

Sources & evidence

ORD record
ord-636ee484bfbb4c78bf7535524fccf29f
Source dataset
uspto-grants-1982_02
Patent number
US04316906

Reaction notes

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