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HRID1448013

反应详情

EQUATION

反应方程式

HRID 1448013 的结构方程式

REACTANTS

反应物

3
结构：O=[N+]([O-])c1ccc(Cl)cc1
HCID7474

1-Chloro-4-nitrobenzene

C6H4ClNO2

结构：O=C([O-])[O-].[Na+].[Na+]
HCID10340

Carbonic acid sodium salt (1:2)

CNa2O3

结构：O=N[O-].[Na+]
HCID23668193

Sodium Nitrite

NNaO2

PRODUCTS

生成物

1
结构：O=[N+]([O-])c1ccc(Oc2ccc([N+](=O)[O-])cc2)cc1
HCID7568

1,1'-Oxybis(4-nitrobenzene)

C12H8N2O5

收率 93.8%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CCCCCCCCCCCCCCCC[P+](CCCC)(CCCC)CCCC.[Br-]
催化剂HCID84716

Phosphonium, tributylhexadecyl-, bromide (1:1)

C28H60BrP

结构：O
溶剂HCID962

Water

H2O

CONDITIONS

反应条件

温度
140 °C

PROCEDURE

实验过程

A mixture of 69 g (1.0 mol) of sodium nitrite, 53 g (0.5 mol) of sodium carbonate, 5 g (0.01 mol) of hexadecyltributyl-phosphonium bromide, 220 ml of water and 78.5 g (0.5 mol) of 4-chloro-nitrobenzene is heated to 140° C. for 7 hours. After cooling, the solid product is filtered off and washed, first with a little dilute hydrochloric acid and then with a little alcohol. After drying, 61 g (91.5% of theory) of 4,4'-dinitrodiphenyl ether (melting point: 139°-140° C.) are obtained.

WORKUP

后处理

  1. temperatureAfter cooling
  2. filtrationthe solid product is filtered off
  3. washwashed, first with a little dilute hydrochloric acid
  4. customAfter drying