HCID 5070074, compound → HCID 86736739, compound

HRID 1448023Notes

Reaction equation

HRID 1448023 reaction equation
[C:1]([OH:4])(=[O:3])[CH3:2].[C:5]([OH:8])(=[O:7])[CH3:6].[OH:9][C@@H:10]1[CH2:35][CH2:34][C@@:33]2([CH3:36])[C@H:12]([C@@H:13]([OH:38])[CH2:14][C@@H:15]3[C@@H:32]2[CH2:31][CH2:30][C@@:29]2([CH3:37])[C@H:16]3[CH2:17][CH2:18][C@@H:19]2[C@H:20]([CH3:28])[CH2:21][CH2:22][C:23](=[O:27])[CH:24]([CH3:26])[CH3:25])[CH2:11]1.[BH4-].[Ca+2].[BH4-]>>[C:1]([OH:4])(=[O:3])[CH3:2].[C:5]([OH:8])(=[O:7])[CH3:6].[OH:9][C@@H:10]1[CH2:35][CH2:34][C@@:33]2([CH3:36])[C@H:12]([C@@H:13]([OH:38])[CH2:14][C@@H:15]3[C@@H:32]2[CH2:31][CH2:30][C@@:29]2([CH3:37])[C@H:16]3[CH2:17][CH2:18][C@@H:19]2[C@H:20]([CH3:28])[CH2:21][CH2:22][CH:23]([OH:27])[CH:24]([CH3:26])[CH3:25])[CH2:11]1

Participants

3

Reactant 2

HCID 5070074HCID 5070074, compoundHCID 86736737HCID 86736737, compound

Product 1

HCID 86736739HCID 86736739, compound

Procedure

3α,6α-Dihydroxy-5β-cholestan-24-one diacetate was treated with calcium borohydride to give 3α,6α,24-trihydroxy-5β-cholestane diacetate.

Sources & evidence

ORD record
ord-7598c5484da842829ab2ec5f9d3598e0
Source dataset
uspto-grants-1979_12
Patent number
US04179452

Reaction notes

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