HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 53726423, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | N-methyl-N-(2,4-dimethyl-3-oxo-2-pentanesulfenyl)carbamoyl chloride | HCID 54024146 | — |
| Reactant | N-1,4-Dithian-2-ylidenehydroxylamine | HCID 71364189 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | HCID 53726423 | HCID 53726423 | — |
Reaction Steps
Prepared as in Example 1 by reacting 8.0 g (0.053 m) of 2-oximino-1,4-dithiane, 15.2 g (0.058 m) of N-methyl-N-(2,4-dimethyl-3-oxo-2-pentanesulfenyl)carbamoyl chloride and 5.42 g (0.053 m) of triethylamine in 100 ml of dioxane. The product crystallized from isopropyl ether-ethyl acetate to yield 4.3 g of a white solid, (m.p. 80°-82° C.) Recrystallization raised the melting point to 85°-86° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04179514 |
| Source dataset | uspto-grants-1979_12 |
| ORD ID | ord-b3314970f6a2492ca88cfbb8531c9eb5 |
| Source note | uspto-grants-1979_12 |