HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → 4-[[O-[N-methyl-N-(2,4-dimethyl-3-oxo-2-pentanesulfenyl)carbamoyl]oximino]]-5-methyl-1,3-oxathiolane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | N-methyl-N-(2,4-dimethyl-3-oxo-2-pentanesulfenyl)carbamoyl chloride | HCID 54024146 | — |
| Reactant | N-(5-Methyl-1,3-oxathiolan-4-ylidene)hydroxylamine | HCID 71364792 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | 4-[[O-[N-methyl-N-(2,4-dimethyl-3-oxo-2-pentanesulfenyl)carbamoyl]oximino]]-5-methyl-1,3-oxathiolane | HCID 53864579 | — |
Reaction Steps
Prepared as in Example I by reacting 2.64 g (0.02 m) of 5-methyl-4-oximino-1,3-oxathiolane, 4.47 g (0.02 m) of N-methyl-N-(2,4-dimethyl-3-oxo-2-pentanesulfenyl)carbamoyl chloride and 2.02 g (0.02 m) of triethylamine in 25 ml of dioxane. Crystallized from isopropyl etherto yield 1.2 g of a white solid, m.p. 90°-92° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04179514 |
| Source dataset | uspto-grants-1979_12 |
| ORD ID | ord-7be04c1ced1741a68f9c65a8ca53ac4b |
| Source note | uspto-grants-1979_12 |