HRID1448756

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID70555

Benzenamine, 4-ethoxy-N-phenyl-

C14H15NO

结构：CCN(Cc1ccccc1)c1ccc(C(=O)c2ccccc2C(=O)O)cc1

HCID54008950

2-{4-[Benzyl(ethyl)amino]benzoyl}benzoic acid

C23H21NO3

PRODUCTS

生成物

结构：CCOc1ccc(N(c2ccccc2)C2(c3ccc(N(CC)Cc4ccccc4)cc3)OC(=O)c3ccccc32)cc1

HCID22174173

未命名化合物

收率 93%

PROCEDURE

实验过程

Following a procedure similar to that described in Example 2 but employing 5.4 g of 2-[4-(ethylbenzylamino)benzoyl]-benzoic acid and 3.1 g of 4-ethoxy-N-phenylaniline there was obtained 7.5 g of 3-[4-(ethylbenzylamino)phenyl]-3-[(4-ethoxyphenyl)phenylamino]phthalide, m.p. 163°-173° C. A toluene solution of the product contacted with acidic clay or phenolic resin developed an orange-colored image.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7163838f37dc43a49279b4eff4f55d24
来源数据集: uspto-grants-1980_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04187223
来源说明: uspto-grants-1980_02

反应 SMILES

[CH2:1]([N:3]([CH2:21][C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)[C:4]1[CH:20]=[CH:19][C:7]([C:8]([C:10]2[CH:18]=[CH:17][CH:16]=[CH:15][C:11]=2[C:12](O)=[O:13])=[O:9])=[CH:6][CH:5]=1)[CH3:2].[CH2:28]([O:30][C:31]1[CH:43]=[CH:42][C:34]([NH:35][C:36]2[CH:41]=[CH:40][CH:39]=[CH:38][CH:37]=2)=[CH:33][CH:32]=1)[CH3:29]>>[CH2:1]([N:3]([CH2:21][C:22]1[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1)[C:4]1[CH:5]=[CH:6][C:7]([C:8]2([N:35]([C:34]3[CH:42]=[CH:43][C:31]([O:30][CH2:28][CH3:29])=[CH:32][CH:33]=3)[C:36]3[CH:41]=[CH:40][CH:39]=[CH:38][CH:37]=3)[C:10]3[C:11](=[CH:15][CH:16]=[CH:17][CH:18]=3)[C:12](=[O:13])[O:9]2)=[CH:19][CH:20]=1)[CH3:2]