Sodium Hydroxide → 3151-48-2

HRID 1448798Notes

Reaction equation

HRID 1448798 reaction equation
[CH2:1]([NH:9][C:10](=[O:16])[C:11]([O:13]CC)=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[OH-].[Na+]>CO>[CH2:1]([NH:9][C:10](=[O:16])[C:11]([OH:13])=[O:12])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

Participants

4

Reactant 2

HCID 14798Sodium HydroxideHCID 10728129HCID 10728129, compound

Product 1

HCID 203757193151-48-2

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To a solution of ethyl N-(n-octyl)oxamate (5 g., 0.022 mole) in methanol (50 ml.) is added slowly NaOH solution (20 ml. of 1 N NaOH diluted with 25 ml. of H2O). After standing for one hour, the mixture is evaporated until the residue is mainly solid. 6 N HCl solution (75 ml.) is added. After stirring for 1 hour the solids are removed by filtration and dried. The yield of N-(n-octyl)oxamic is 3.85 g. (m.p. 89°-93° C.).

Workup

  1. customthe mixture is evaporated until the residue
  2. addition6 N HCl solution (75 ml.) is added
  3. customare removed by filtration
  4. customdried

Sources & evidence

ORD record
ord-a847f8af2cf74e01a49807a16ed9a132
Source dataset
uspto-grants-1980_02
Patent number
US04187315

Reaction notes

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