HuagongsheHuagongshe Chemistry Print Report · For research reference only
Tributylstannane → HCID 10982269, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Tributylstannane | HCID 5948 | — |
| Reactant | Azobisisobutyronitrile | HCID 6547 | — |
| Reactant | 1-Octyne | HCID 12370 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 10982269 | HCID 10982269 | — |
Reaction Steps
A solution of 10.0 g (0.0908 mol) of 1-octyne, 60 ml of anhydrous toluene, 230 mg of azobisisobutylonitrile (AIBN), and 25 (0.0943 mol) of tri-n-butyltin hydride is refluxed under an argon atomosphere for 3 hours. The reaction mixture is cooled to ambient temperature and concentrated in vacuo. The resulting yellow liquid is distilled (bulb to bulb) to give 36.29 (99%) of the stannyl octene as a pale yellow liquid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04189597 |
| Source dataset | uspto-grants-1980_02 |
| ORD ID | ord-c7b0d69f12f14fcfac35f5212049e2b0 |
| Source note | uspto-grants-1980_02 |