Chloromethyl methyl sulfide → HCID 13507982, compound

HRID 1449394Notes

Reaction equation

HRID 1449394 reaction equation
[CH3:1][S:2]CCl.[CH2:5]([S:8][C:9]1[NH:10][C:11]([C:22]2[CH:27]=[CH:26][C:25]([O:28][CH3:29])=[CH:24][CH:23]=2)=[C:12]([C:14]2[CH:19]=[CH:18][C:17]([O:20][CH3:21])=[CH:16][CH:15]=2)[N:13]=1)C=C>>[CH3:29][O:28][C:25]1[CH:24]=[CH:23][C:22]([C:11]2[N:10]=[C:9]([S:8][CH2:5][S:2][CH3:1])[NH:13][C:12]=2[C:14]2[CH:19]=[CH:18][C:17]([O:20][CH3:21])=[CH:16][CH:15]=2)=[CH:27][CH:26]=1

Participants

3

Reactant 2

HCID 16916Chloromethyl methyl sulfideHCID 13507978HCID 13507978, compound

Product 1

HCID 13507982HCID 13507982, compound

Procedure

By substituting chloromethyl methyl sulfide for the allyl bromide of Example 11 one obtains as product 4,5-bis-(4-methoxyphenyl)-2-(methylthiomethylthio)imidazole, m.p. 171°-172°.

Sources & evidence

ORD record
ord-95cb77c94d024042a32399b5ee938900
Source dataset
uspto-grants-1980_02
Patent number
US04190666

Reaction notes

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