HCID 13508094, compound → HCID 13508143, compound

HRID 1449397Notes

Reaction equation

HRID 1449397 reaction equation
Br[CH:2]([F:24])[C:3]([F:23])([F:22])[S:4][C:5]1[NH:6][C:7]([C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)=[C:8]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[N:9]=1.BrC[CH2+](C(F)(F)CF)C1NC(C2C=CC(OC)=CC=2)=C(C2C=CC(OC)=CC=2)N=1>>[C:16]1([C:7]2[N:6]=[C:5]([S:4][C:3]([F:22])([F:23])[CH2:2][F:24])[NH:9][C:8]=2[C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)[CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=1

Participants

2

Reactant 1

HCID 13508094HCID 13508094, compound

Product 1

HCID 13508143HCID 13508143, compound

Procedure

By substituting 2-(2-bromo-1,1,2-trifluoroethylthio)-4,5-diphenylimidazole for the 2-(2-bromo-1,1,2-trifluoroethylethio)-4,5-bis(4-methoxyphenyl)imidazole of Example 20, one obtains as product 4,5-diphenyl-2-(1,1,2-trifluoroethylthio)imidazole, m.p. 225°-226.5°.

Sources & evidence

ORD record
ord-5eb7df4f7cde41be98890f05c2c7c6c8
Source dataset
uspto-grants-1980_02
Patent number
US04190666

Reaction notes

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