Water → HCID 20349431, compound

HRID 1449400Notes

Reaction equation

[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[N:9]=[C:10]([S:20]([C:23]([F:28])([F:27])[CH:24]([F:26])[F:25])(=[O:22])=[O:21])[NH:11][C:12]=2[C:13]2[CH:18]=[CH:17][C:16]([OH:19])=[CH:15][CH:14]=2)=[CH:4][CH:3]=1.[C:29](OC(=O)C)(=[O:31])[CH3:30].N1[CH:41]=[CH:40]C=CC=1.[OH2:42]>>[C:29]([O:1][C:2]1[CH:3]=[CH:4][C:5]([C:8]2[N:9]=[C:10]([S:20]([C:23]([F:27])([F:28])[CH:24]([F:26])[F:25])(=[O:21])=[O:22])[NH:11][C:12]=2[C:13]2[CH:14]=[CH:15][C:16]([O:19][C:40](=[O:42])[CH3:41])=[CH:17][CH:18]=2)=[CH:6][CH:7]=1)(=[O:31])[CH3:30]

Participants

Reactant 4

HCID 962Water

HCID 1049Pyridine

HCID 7918Acetic Anhydride

HCID 20349430HCID 20349430, compound

Product 1

HCID 20349431HCID 20349431, compound

Procedure

A mixture of 4,5-bis(4-hydroxyphenyl)-2-(1,1,2,2-tetrafluoroethylsulfonyl)imidazole (0.1 mole), acetic anhydride (0.2 mole), and pyridine (500 ml.) is heated for two hrs. on the steam bath. On pouring the mixture into water there is obtained as product 4,5-bis(4-acetoxyphenyl)-2-(1,1,2,2-tetrafluoroethylsulfonyl)imidazole.

Workup

temperatureis heated for two hrs

Sources & evidence

ORD record: ord-acd61d0b92f1483c9e04a4caf655fda1
Source dataset: uspto-grants-1980_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04190666

Reaction notes

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