化工社化工社 化学情報印刷レポート · 研究参考用
1-Butanaminium, N,N,N-tributyl-, azide → Ethanethioic acid cis-(+/-)-S-[5-(Azidomethyl)tetrahydro-3-furanyl]ester
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Butanaminium, N,N,N-tributyl-, azide | HCID 5743232 | — |
| 反応物 | Ethanethioic acid cis-(+/-)-S-[tetrahydro-5-[[[(trifluoromethyl)-sulfonyl]oxy]methyl]-3-furanyl]ester | HCID 86750330 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | Ethanethioic acid cis-(+/-)-S-[5-(Azidomethyl)tetrahydro-3-furanyl]ester | HCID 86750331 | 87.8% |
反応手順
The title compound is prepared by the procedure of Example 43 using 0.560 g of product from Example 60 in 2 ml of methylene chloride, 0.569 g of tetrabutylammonium azide in 2 ml of methylene chloride to give 0.321 g of the desired product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05602118 |
| 出典データセット | uspto-grants-1997_02 |
| ORD ID | ord-b5b00e01f41546b0b05bccd21f7a324d |
| 出典メモ | uspto-grants-1997_02 |