4-Bromo-2-ethylphenol → 5-Bromo-1,3-dichloro-2-ethoxybenzene

HRID 1453236Notes

Reaction equation

HRID 1453236 reaction equation
[Br:1][C:2]1[CH:3]=[C:4]([Cl:10])[CH2:5][C:6]([Cl:9])(O)[CH:7]=1.BrC1C=C[C:15]([OH:18])=[C:14](CC)C=1>>[CH2:15]([O:18][C:5]1[C:4]([Cl:10])=[CH:3][C:2]([Br:1])=[CH:7][C:6]=1[Cl:9])[CH3:14]

Participants

3

Reactant 2

HCID 878774-Bromo-2-ethylphenolHCID 68866369HCID 68866369, compound

Product 1

HCID 467393745-Bromo-1,3-dichloro-2-ethoxybenzene

Procedure

The title compound was prepared analogously to step 2 in Example A(125), where 5-Bromo-1,3-dichloro-phenol was substituted in place of 4-bromo-2-ethyl-phenol in that example. 1H NMR (400 MHz, CDCl3): δ 1.46 (t, J=7.0 Hz, 3H), 4.10 (q, J=7 Hz, 2H), 7.09 (s, 2H).

Sources & evidence

ORD record
ord-b86e1c880c4d47cc9f8dc9be10de9d86
Source dataset
uspto-grants-2009_01
Patent number
US07473790B2

Reaction notes

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