HRID1454749

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CC(C)CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]

HCID2759379

(3-Methylbutyl)(triphenyl)phosphanium bromide

C23H26BrP

HCID5462222

Potassium

HCID86620810

未命名化合物

PRODUCTS

生成物

结构：CC(C)CC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.CCCCCCCCOC(=O)C(C#N)C=O

HCID86620809

未命名化合物

PROCEDURE

实验过程

CDP-8 was prepared similar to the method used to prepare CDP-2 from potassium salt of 3-oxo-2-cyanopropanoic acid n-octyl ester and isoamyltriphenylphosphonium bromide in quantitative yield as a viscose orange color oily residue.

WORKUP

后处理

customwas prepared similar to the method

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-ddbf3463a06c4f38b63a00d0409b8614
来源数据集: uspto-grants-2009_01
DOI: 10.6084/m9.figshare.5104873.v1
专利: US07482113B2
来源说明: uspto-grants-2009_01

反应 SMILES

[K].[CH2:2]([O:10][C:11](=[O:17])[CH:12]([C:15]#[N:16])[CH:13]=[O:14])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[Br-].[CH2:19]([P+:24]([C:37]1[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1)([C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=1)[C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1)[CH2:20][CH:21]([CH3:23])[CH3:22]>>[CH2:19]([P+:24]([C:37]1[CH:42]=[CH:41][CH:40]=[CH:39][CH:38]=1)([C:25]1[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=1)[C:31]1[CH:36]=[CH:35][CH:34]=[CH:33][CH:32]=1)[CH2:20][CH:21]([CH3:23])[CH3:22].[CH2:2]([O:10][C:11](=[O:17])[CH:12]([C:15]#[N:16])[CH:13]=[O:14])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]