2,5-Dibromopyridine → HCID 68956767, compound
Reaction equation
[CH3:1][S:2][C:3]1[CH:8]=[CH:7][C:6](B(O)O)=[CH:5][CH:4]=1.Br[C:13]1[CH:18]=[CH:17][C:16]([Br:19])=[CH:15][N:14]=1>>[Br:19][C:16]1[CH:17]=[CH:18][C:13]([C:6]2[CH:7]=[CH:8][C:3]([S:2][CH3:1])=[CH:4][CH:5]=2)=[N:14][CH:15]=1Participants
3
Procedure
Prepared according to the procedure Coupling-2 using [4-(methylthio)phenyl]boronic acid and 2,5-dibromo pyridine afforded the title compound in a mixture of isomer containing 2-bromo-5-[4-(methylthio)phenyl]pyridine.
Workup
- customPrepared
Sources & evidence
- ORD record
- ord-b102bc3a1749497e95de24e35aab3344
- Source dataset
- uspto-grants-2009_01
- Patent number
- US07482456B2
Reaction notes
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