HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,2-Dibromoethane → Ethyl 1-acetylcyclopropane-1-carboxylate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,2-Dibromoethane | HCID 7839 | — |
| Reactant | Ethyl Acetoacetate | HCID 8868 | — |
| Product | Ethyl 1-acetylcyclopropane-1-carboxylate | HCID 234183 | — |
Reaction Steps
Ethyl acetoacetate is allowed to react with 1,2-dibromoethane to obtain ethyl 1-acetylcyclopropanecarboxylate. Next, ethyl 1-acetylcyclopropanecarboxylate is allowed to react with zinc powder and ethylbromoacetate to give ethyl 1-ethoxycarbonyl-β-hydroxy-β-methyl-cyclopropanoate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05849757 |
| Source dataset | uspto-grants-1998_12 |
| ORD ID | ord-a60a9254318e4950b03495dda14734a9 |
| Source note | uspto-grants-1998_12 |