HCID 10041597, compound → HCID 10087144, compound

HRID 1458328Notes

Reaction equation

HRID 1458328 reaction equation
[CH3:1][C@H:2]1[C:12]([CH:13]=[CH2:14])=[CH:11][C:9](=[O:10])[C@H:8]2[C@H:3]1[CH2:4][CH2:5][C@H:6]1[C:19]([CH3:21])([CH3:20])[C:17](=[O:18])[C@@H:16]([OH:22])[CH2:15][C@@:7]12[CH3:23].C[C@H]1C(C=C)=CC(=O)[C@H]2[C@H]1CC[C@H]1C(C)(C)[C@@H](O)[C@@H](O)[C@@H](O)[C@@]12C.C[C@H]1C(C=C)=CC(=O)[C@H]2[C@H]1CC[C@H]1C(C)(C)[C@@H](O)C[C@@H](O)[C@@]12C>>[CH3:1][C@H:2]1[C:12]([CH:13]=[CH2:14])=[CH:11][C:9](=[O:10])[C@H:8]2[C@H:3]1[CH2:4][CH2:5][C@H:6]1[C:19]([CH3:21])([CH3:20])[C@@H:17]([OH:18])[C:16](=[O:22])[CH2:15][C@@:7]12[CH3:23]

Participants

4

Reactant 3

HCID 10041597HCID 10041597, compoundHCID 10313699HCID 10313699, compoundHCID 10427023HCID 10427023, compound

Product 1

HCID 10087144HCID 10087144, compoundYield 40%

Procedure

According to fractionating by the above three-step high performance liquid chromatography (HPLC), about 20 mg of phytocassane A, about 10 mg of phytocassane B, about 3 mg of phytocassane C and about 8 mg of phytocassane D were obtained as a single phytocassane fraction.

Sources & evidence

ORD record
ord-0650d282e10d4b6ab8cf8343ebbcca00
Source dataset
uspto-grants-1998_12
Patent number
US05849956

Reaction notes

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