HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Oxalate → 6-Chloro-1-cyclohexyl-2,3(1H,4H)-quinoxalinedione
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Oxalate | HCID 7268 | — |
| Reactant | 4-Chloro-N1-cyclohexylbenzene-1,2-diamine | HCID 22097150 | — |
| Product | 6-Chloro-1-cyclohexyl-2,3(1H,4H)-quinoxalinedione | HCID 22097192 | 63% |
Reaction Steps
34.5 g (0.15 mol) of 2-amino-4-chloro-N-cyclohexylaniline were refluxed in 500 ml of diethyl oxalate for 4 h. After cooling, the precipitate was filtered off with suction, washed with n-pentane and dried to yield 26.8 g (63%) of the product. Melting point 265°-266° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05852017 |
| Source dataset | uspto-grants-1998_12 |
| ORD ID | ord-8c74a6d18de34649aba8c9908fc12b47 |
| Source note | uspto-grants-1998_12 |