Potassium Nitrate → HCID 22097129, compound

HRID 1458848Notes

Reaction equation

HRID 1458848 reaction equation
[Cl:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][CH:11]=1)[N:8]([CH2:12][CH:13]([CH2:16][CH3:17])[CH2:14][CH3:15])[C:7](=[O:18])[C:6](=[O:19])[NH:5]2.[N+:20]([O-])([O-:22])=[O:21].[K+]>S(=O)(=O)(O)O>[Cl:1][C:2]1[CH:3]=[C:4]2[C:9](=[CH:10][C:11]=1[N+:20]([O-:22])=[O:21])[N:8]([CH2:12][CH:13]([CH2:14][CH3:15])[CH2:16][CH3:17])[C:7](=[O:18])[C:6](=[O:19])[NH:5]2

Participants

4

Reactant 2

HCID 24434Potassium NitrateHCID 22097139HCID 22097139, compound

Product 1

HCID 22097129HCID 22097129, compoundYield 91%

Reagents, catalysts & solvents 1

HCID 1118Sulfuric AcidSolvent

Conditions

Temperature
0 °C

Procedure

30 g (0.106 mol) of 6-chloro-1-(2-ethylbutyl)-2,3(1H,4H)-quinoxalinedione were dissolved in 350 ml of concentrated sulfuric acid and cooled to 0°C. Then, at 0° C., 10.8 g of potassium nitrate were added a little at a time, and the solution was stirred for 1.5 h. The mixture was then poured into ice-water, and the precipitate was filtered off with suction, washed with water and dried to yield 31 g (91%) of the product. Melting point 232°-233° C.

Workup

  1. filtrationthe precipitate was filtered off with suction
  2. washwashed with water
  3. customdried

Sources & evidence

ORD record
ord-aee6d0ce146f4dd985296c07d943c085
Source dataset
uspto-grants-1998_12
Patent number
US05852017

Reaction notes

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