HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trimethyl borate → [4-(Dodecyloxy)phenyl]boronic acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trimethyl borate | HCID 8470 | — |
| Reactant | HCID 287462 | HCID 287462 | — |
| Reactant | 4-n-Octyloxyphenylboronic Acid (contains varying amounts of Anhydride) | HCID 3977284 | — |
| Reactant | Butyllithium | HCID 178418339 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | [4-(Dodecyloxy)phenyl]boronic acid | HCID 15790446 | — |
Reaction Steps
Quantities: compound 30 (15.00 g, 0.047 mol) in anhydrous THF (150 ml), n-butyllithium (20 ml, 2.5M in hexane, 0.050 mol), trimethyl borate (9.79 g, 0.094 mol) in anhydrous THF (50 ml). The experimental procedure was as described for the preparation of compound 33.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05853613 |
| Source dataset | uspto-grants-1998_12 |
| ORD ID | ord-a5e5c5b422d04fe1a380128b73001908 |
| Source note | uspto-grants-1998_12 |