HuagongsheHuagongshe Chemistry Print Report · For research reference only
Triethylamine → HCID 19801137, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | P,P-Diphenylphosphinic azide | HCID 199401 | — |
| Reactant | HCID 19107020 | HCID 19107020 | — |
| Solvent | Toluene | HCID 1140 | — |
| Product | HCID 19801137 | HCID 19801137 | 66% |
Reaction Steps
A solution of the compound from Example 52 (1 g, 4.1 mmol) and diphenylphosphorylazide (1.25 g, 4.5 mmol) in triethylamine (0.6 g) and 30 ml toluene was heated at 110° C. for 30 minutes. Workup and silica gel chromatography gave the title compound (0.65 g, 66%) as a yellow syrup.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05071853 |
| Source dataset | uspto-grants-1991_12 |
| ORD ID | ord-0d6d9d3784a341c99afbb25b9a648ee3 |
| Source note | uspto-grants-1991_12 |