HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Ether → HCID 19979565, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | 3,4-Dihydro-2H-pyrano[3,2-c]pyridine | HCID 15557570 | — |
| Product | HCID 19979565 | HCID 19979565 | — |
Reaction Steps
To 2.45 g (18.15 mmol) of 6-azachroman (prepared as described in Sliwa, et al., J. Het. Chem. 12:809 (1975)) in 25 ml of ethyl ether is added 61 ml of 1.5 M methyllithium-lithium bromide complex. The mixture is heated at reflux for 17 hours and worked up as described above to yield 0.800 g of the titled compound. High resolution mass spectrum: Calcd. for C9H11NO: 149.0841; Found: 149.0834.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05077407 |
| Source dataset | uspto-grants-1991_12 |
| ORD ID | ord-caf700c35e034d0097dc80ed3b05a2b5 |
| Source note | uspto-grants-1991_12 |