1,3-Dinitrobenzene → 3-Nitroanisole

HRID 1461900Notes

Reaction equation

HRID 1461900 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([N+]([O-])=O)[CH:5]=1)([O-:3])=[O:2].[CH3:13][O-:14].[Na+]>ClC1C=CC=CC=1>[N+:1]([C:4]1[CH:5]=[C:6]([O:14][CH3:13])[CH:7]=[CH:8][CH:9]=1)([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 74521,3-DinitrobenzeneHCID 10942334Sodium Methoxide

Product 1

HCID 111403-Nitroanisole

Reagents, catalysts & solvents 1

HCID 7964ChlorobenzeneSolvent

Procedure

m-Nitroanisol was prepared by reacting m-dinitrobenzene with sodium methoxide in chlorobenzene in the presence of phase-transfer catalysts (F. Montanari et al., Chem. & Ind., (1982), 412).

Sources & evidence

ORD record
ord-b5afc7858bc3451bb4cf2bcf5c1b8c8e
Source dataset
uspto-grants-1991_12
Patent number
US05077436

Reaction notes

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