Methylhydrazine → HCID 13320508, compound

HRID 1462351Notes

Reaction equation

HRID 1462351 reaction equation
[CH3:1][NH:2][NH2:3].CO[C:6]1[N:11]=[CH:10][N:9]([C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[C:8](=[O:18])[N:7]=1>C(O)C>[CH3:1][NH:2][NH:3][C:6]1[N:11]=[CH:10][N:9]([C:12]2[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=2)[C:8](=[O:18])[N:7]=1

Participants

4

Reactant 2

HCID 6061MethylhydrazineHCID 130540494-Methoxy-1-phenyl-1,3,5-triazin-2(1H)-one

Product 1

HCID 13320508HCID 13320508, compoundYield 63.1%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

2.4 ml of methylhydrazine dissolved in 10 ml of absolute ethanol are added to a suspension of 4-methoxy-1-phenyl-1,2-dihydro-1,3,5-triazin-2-one (4.60 g) in 100 ml of absolute ethanol and stirred for one hour. The solid product is filtered, washed with ether and dried to give 3.10 g (63.1%) of 4-methylhydrazino-1-phenyl-s-triazin-2-one, m.p. 219° C.

Workup

  1. filtrationThe solid product is filtered
  2. washwashed with ether
  3. customdried

Sources & evidence

ORD record
ord-a67cf2b1f5654ac0b56e3ff8ceb438fa
Source dataset
uspto-grants-1984_07
Patent number
US04460585

Reaction notes

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