4-Amino-2,2,6,6-tetramethylpiperidine → HCID 19090265, compound

HRID 1463424Notes

Reaction equation

HRID 1463424 reaction equation
[C:1]([O:6]CC)(=O)[C:2]([NH2:4])=[O:3].[NH2:9][CH:10]1[CH2:15][C:14]([CH3:17])([CH3:16])[NH:13][C:12]([CH3:19])([CH3:18])[CH2:11]1>>[CH3:18][C:12]1([CH3:19])[CH2:11][CH:10]([NH:9][C:1]([C:2]([NH2:4])=[O:3])=[O:6])[CH2:15][C:14]([CH3:17])([CH3:16])[NH:13]1

Participants

3

Reactant 2

HCID 375244-Amino-2,2,6,6-tetramethylpiperidineHCID 69238Ethyl oxamate

Product 1

HCID 19090265HCID 19090265, compound

Procedure

The filtrate was transferred back to the 250 ml 3-neck flask and another 30.5g of ethyl oxamate was added. An additional 39g of 4-amino-2,2,6,6-tetramethylpiperidine were added over 7 minutes as the temperature slowly rose to 28° C. The reaction was stirred 3 hours and filtered. After air drying overnight, the filter cake weighed 50.0 g and had a melting point of 198°-200° C.

Workup

  1. customslowly rose to 28° C
  2. filtrationfiltered
  3. customAfter air drying overnight

Sources & evidence

ORD record
ord-dfbfa37acbe34ed18cff5db73641776e
Source dataset
uspto-grants-1994_04
Patent number
US05300545

Reaction notes

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