Ethanol → HCID 88444498, compound

HRID 1463578Notes

Reaction equation

HRID 1463578 reaction equation
[CH2:1]([N:3]([CH2:6]/[CH:7]=[CH:8]\[CH2:9]/[CH:10]=[CH:11]\[CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:4][CH3:5])[CH3:2].C([OH:19])C>>[CH2:1]([N+:3]([O-:19])([CH2:6]/[CH:7]=[CH:8]\[CH2:9]/[CH:10]=[CH:11]\[CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:4][CH3:5])[CH3:2]

Participants

3

Reactant 2

HCID 702EthanolHCID 88406226HCID 88406226, compound

Product 1

HCID 88444498HCID 88444498, compoundYield 95%

Procedure

4 G (18 mmole) of N,N-diethyl-undeca-2Z,5Z-dienyl-amine in 10 ml of ethanol were placed in a 25 ml flask under nitrogen and 4 ml of 70% oxygenated water were added thereto. The reaction mixture was maintained under stirring for 1 h and then left to rest at room temperature for 18 h. After evaporation, it was retaken with ethyl acetate and the organic phase, once separated, was washed with a saturated solution of NaCl, dried over Na2SO4 and evaporated to provide 4.09 g of N,N-diethyl-undeca-2Z,5Z-dienyl-amine N-oxide (yield: 95%).

Workup

  1. custom4 ml of 70% oxygenated water
  2. additionwere added
  3. temperatureThe reaction mixture was maintained
  4. waitleft
  5. waitto rest at room temperature for 18 h
  6. customAfter evaporation, it
  7. customthe organic phase, once separated
  8. washwas washed with a saturated solution of NaCl
  9. dry with materialdried over Na2SO4
  10. customevaporated

Sources & evidence

ORD record
ord-6b0befc9a02a410694b615aa438f967f
Source dataset
uspto-grants-1994_04
Patent number
US05300716

Reaction notes

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