HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethanol → Ethyl hydrogen phenylphosphonite
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethanol | HCID 702 | — |
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | Phenyl phosphorus dichloride | HCID 12573 | — |
| Product | Ethyl hydrogen phenylphosphonite | HCID 10920933 | — |
Reaction Steps
To a solution of 270 ml of phenyldichlorophosphine in 1000 ml of diethylether is added with stirring and cooling with ice a solution of 280 ml of ethanol and 280 ml of triethylamine in 500 ml of diethylether. After stirring for 14 hours at 20° the precipitate is filtered off and the filtrate is fractionally distilled. There is obtained phenylphosphonous acid-ethylester as a colorless liquid, b.p. 83°-85°/6 Pa.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05300679 |
| Source dataset | uspto-grants-1994_04 |
| ORD ID | ord-a7e39ab5c47f4bd5b41d7db1896b756d |
| Source note | uspto-grants-1994_04 |