HuagongsheHuagongshe Chemistry Print Report · For research reference only
Acrylonitrile → Ethyl 2-cyanoethyl(phenyl)phosphinate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Acrylonitrile | HCID 7855 | — |
| Reactant | Sodium ethoxide | HCID 2723922 | — |
| Reactant | Ethyl hydrogen phenylphosphonite | HCID 10920933 | — |
| Product | Ethyl 2-cyanoethyl(phenyl)phosphinate | HCID 19090907 | — |
Reaction Steps
To 42.45 g of phenylphosphonous acid-ethylester and 16.45 ml of acrylonitrile are added with stirring 5 ml of sodium ethylate (1 molar). The reaction is exothermic. After 1 hour stirring at 20° the mixture is fractionally distilled. There is obtained ethyl 2-cyanoethyl(phenyl)phosphinate as a colorless oil, b.p. 134°-136°/7 Pa.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05300679 |
| Source dataset | uspto-grants-1994_04 |
| ORD ID | ord-d43116e1c33d4ac2947dda5cc561f99a |
| Source note | uspto-grants-1994_04 |