HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzene → 4-Methylthio-2-nitrobiphenyl
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzene | HCID 241 | — |
| Reactant | Pentyl nitrite | HCID 10026 | — |
| Reactant | 4-(Methylsulfanyl)-2-nitroaniline | HCID 10888607 | — |
| Product | 4-Methylthio-2-nitrobiphenyl | HCID 19089266 | — |
Reaction Steps
A mixture of 4-methylthio-2-nitroaniline (27.6 g), amyl nitrite (22.5 ml) and cupric chloride (4.5 g) in dry benzene (250 ml) was heated under reflux for 9 hours to give 4-methylthio-2-nitrobiphenyl (m.p. 51°-52° C.).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05302720 |
| Source dataset | uspto-grants-1994_04 |
| ORD ID | ord-82a1b94d235d48fcb4c5b520f5fcce0c |
| Source note | uspto-grants-1994_04 |