HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1464712Generated: October 31, 2026
o-Cumenyl chloroformate → Benzene, 1-chloro-2-(1-methylethyl)-
https://huagongshe.com/reaction/1464712
Participants
| Role | Name | HCID | Charge |
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| Reactant | o-Cumenyl chloroformate | HCID 6365464 | — |
| Reactant | Aluminum(III) Chloride | HCID 6451240 | — |
| Product | Benzene, 1-chloro-2-(1-methylethyl)- | HCID 16377 | 20% |
Reaction Steps
0.35 g of anhydrous aluminium chloride was added to 25 g of 2-isopropylphenyl chloroformate and the mixture was heated at 200° C. for 3 hours at normal pressure. The reaction mixture was cooled and worked up as described in Example 1. 2-Isopropylchlorobenzene was obtained in a yield of 20%, which is considerable despite the unfavourable substitution pattern.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US05306849 |
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| Source dataset | uspto-grants-1994_04 |
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| ORD ID | ord-0c4624d1938140769baec1ebe948d82c |
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| Source note | uspto-grants-1994_04 |
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