Acetaldehyde → HCID 19086964, compound

HRID 1464747Notes

Reaction equation

[CH2:1](N(C/C=C/C#CC(C)(C)C)CCNCCOC1C=CC=C(C2C=CSC=2)C=1)C.C(=O)C.[CH2:33]([N:35]([CH2:53]/[CH:54]=[CH:55]/[C:56]#[C:57][C:58]([CH3:61])([CH3:60])[CH3:59])[CH2:36][CH2:37][NH:38][CH2:39]/[CH:40]=[CH:41]/[C:42]1[CH:47]=[CH:46][CH:45]=[C:44]([C:48]2[CH:52]=[CH:51][S:50][CH:49]=2)[CH:43]=1)[CH3:34].C=O>>[CH2:33]([N:35]([CH2:53]/[CH:54]=[CH:55]/[C:56]#[C:57][C:58]([CH3:60])([CH3:59])[CH3:61])[CH2:36][CH2:37][N:38]([CH3:1])[CH2:39]/[CH:40]=[CH:41]/[C:42]1[CH:47]=[CH:46][CH:45]=[C:44]([C:48]2[CH:52]=[CH:51][S:50][CH:49]=2)[CH:43]=1)[CH3:34]

Participants

Reactant 4

HCID 177Acetaldehyde

HCID 712Formaldehyde

HCID 19917004HCID 19917004, compound

HCID 19917115HCID 19917115, compound

Product 1

HCID 19086964HCID 19086964, compound

Procedure

Compounds of Examples 81 and 82 were obtained by performing the same reaction as in Example 80 except that (E)-N'-ethyl-N'-(6,6-dimethyl-2-hepten-4-ynyl)-N-[2-[3-(3-thienyl)phenoxy]ethyl]ethylenediamine or acetaldehyde was used instead of the starting compound, (E, E)-N'-ethyl-N'-(6,6-dimethyl-2-hepten-4-ynyl)-N-[3-[3-(3-thienyl)phenyl]-2-propenyl]ethylenedi-amine or formalin, which was used in the above-mentioned reaction.

Workup

customwas used in the above-mentioned reaction

Sources & evidence

ORD record: ord-90b51e9649e24a4ab40b444dfd4fa905
Source dataset: uspto-grants-1994_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05306728

Reaction notes

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