Methanol → Methyl 4-amino-5-methylthiophene-2-carboxylate

HRID 146564Notes

Reaction equation

HRID 146564 reaction equation
[CH3:14][OH:15].[CH3:1][O:2][C:3](=[O:4])[c:5]1[s:6][c:7]([CH3:13])[c:8]([N+:10]([O-:11])=[O:12])[cH:9]1.[Ni:16]>>[CH3:1][O:2][C:3](=[O:4])[c:5]1[s:6][c:7]([CH3:13])[c:8]([NH2:10])[cH:9]1

Participants

4

Reactant 3

HCID 887MethanolHCID 935NickelHCID 268679Methyl 5-methyl-4-nitrothiophene-2-carboxylate

Product 1

HCID 59640747Methyl 4-amino-5-methylthiophene-2-carboxylate

Sources & evidence

ORD record
ord-f86f00850c974b8ebea3da96c6c80359
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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