HCID 178450862, compound → HCID 66861293, compound

HRID 1465931Notes

Reaction equation

HRID 1465931 reaction equation
C(O[C:6]([C:8]1[N:13]=[C:12](O)[C:11]2[CH:15]=[C:16]([S:18][C:19]3[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=3)[S:17][C:10]=2[C:9]=1[OH:25])=[O:7])CCC.C([O:30][C:31]([C:33]1C(O)=C2C=C(SC3C=CC=CC=3)SC2=C(O)[N:38]=1)=[O:32])CCC>>[OH:25][C:9]1[C:10]2[S:17][C:16]([S:18][C:19]3[CH:20]=[CH:21][CH:22]=[CH:23][CH:24]=3)=[CH:15][C:11]=2[CH:12]=[N:13][C:8]=1[C:6]([NH:38][CH2:33][C:31]([OH:32])=[O:30])=[O:7]

Participants

3

Reactant 2

HCID 178450862HCID 178450862, compoundHCID 178450866HCID 178450866, compound

Product 1

HCID 66861293HCID 66861293, compound

Procedure

The title compound was prepared from a mixture of 4,7-dihydroxy-2-phenylsulfanyl-thieno[3,2-c]pyridine-6-carboxylic acid n-butyl ester and 4,7 dihydroxy-2-phenylsulfanyl-thieno[2,3-c]pyridine-5-carboxylic acid n-butyl ester, example 17.a, under conditions analogous to experimental conditions 5.a. The products were obtained as a mixture of the two isomers; MS: (+) m/z 437.91, 439.91 (M+1, 79Br/81Br).

Workup

  1. customThe products were obtained as a mixture of the two isomers

Sources & evidence

ORD record
ord-fd198f94b480421b8d6d00322b534ac8
Source dataset
uspto-grants-2015_04
Patent number
US09000006B2

Reaction notes

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